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1 H NMR (500 MHz, DMSO- d 6 ) δ 13.02 (s, 1H, N H Ca ), 9.22–9.12 (s, 1H, C H Ar ), 8.80–8.71 (m, 1H, C H Ar ), 8.68–8.62 (m, 1H, N H 2 ), 8.62–8.57 (d, J = 9.1 Hz, 1H, C H Ar ), 8.54–8.49 (d, J = 9.2 Hz, 1H, C H Ar ), 8.43–8.27 (m, 3H, N H 2 + C H Ar ), 8.20–8.13 (t, J = 10.1 Hz, 1H, C H Ar ), 7.76–7.65 (m, 1H, N H 2 ), 7.47 (s, 1H, C H Ar ), 3.59–3.55 (t, 2H, PtOCOC H̲ 2 ), 3.52–3.44 (m, 10H, CH PEG ), 3.44–3.41 (m, 2H, C H̲ 2 OCH 3 ), 3.24 (s, 3H, OC H 3 ), 2.84–2.74 (m, 1H, C H cHex ), 2.67–2.59 (m, 1H, C H cHex ), 2.57–2.53 (t, 2H, PtOCOCH 2 C H̲ 2 ), 2.21–2.10 (m, 2H, C H cHex ), 1.65–1.55 (m, 1H, C H cHex ), 1.54–2.39 (m, 3H, C H cHex ), 1.20–1.08 (m, 2H, C H cHex ) ppm