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pH 7.4) and 50% of (20% ACN, 0.1% FA) at final concentrations of 20 nM to 1 µM and 0.5 µM to 10 µM for GS-CAM-TPP, 50 nM to 1 µM and 0.5 µM to 10 µM for GSS-CAM-TPP supplemented with 25 µM of deuterated internal standards GS-CAM- d 15 TPP and 5 µM of deuterated internal standards GSS-CAM- d 15 TPP